| Product name |
Ethylchloroacetate |
| Molecular formula |
C4H7ClO2
|
| CAS NO. |
105-39-5 |
| Molecular weight |
122.55 |
| Basic Information |
[Product name]: Ethylchloroacetate
[CAS number]: 105-39-5
[Molecular formula]: C4H7ClO2
[Molecular weight]: 122.55
[RTECS number]: AF9110000
[UN Code]: 1181
[Dangerous Goods Code]: 61102
[IMDG Rule Page]: 6147
[Appearance and properties]: colorless liquid with pungent odor.
[Hazard category]: Category 6.1 Toxicant
[Packaging Mark of Dangerous Goods]: 14
[Packing type]: II
[Solubility]: insoluble in water, soluble in ethanol, ether, benzene.
[Main Uses]: used as a solvent for organic synthesis.
|
| Physical and chemical properties |
[Critical temperature (° C)]:
[Critical pressure (MPa)]:
[Saturated vapor pressure (kPa)]: 1.33 / 38 ° C
[Heat of combustion (kj / mol)]:
[Melting point (° C)]: -26
[Boiling point (° C)]: 143
[Flash point (° C)]: 54
[Relative density (water == 1)]: 1.16
[Relative density (air = 1)]: 4.3
[Autoignition temperature (° C)]: NA
[Lower Explosive Limit (V%)]: NA
[Upper Explosive Limit (V%)]: NA
|
| Hazardous characteristics |
[Hazardous characteristics]: case of high fever, open flame or contact with oxidants, causing the risk of combustion. Toxic decomposition of corrosive gases.
[Flammability]: Flammable
[Toxic]: is a high toxic category
LD50: 50 mg / kg (rat oral); 230 mg / kg (rabbit percutaneous)
LC50:
[Stability]: Stable
[Polymer Hazards]: Can not occur
[Building fire classification]: B
[Combustion (decomposition) products]: carbon monoxide, carbon dioxide, hydrogen chloride.
[Contraindications]: acids, alkalis, strong oxidants, strong reducing agents.
[Fire fighting methods]: foam, carbon dioxide, sand.
|
| Human body harm and protection |
[Health hazards]: the eyes, respiratory mucosa have a strong stimulating effect, severe cases can cause pulmonary edema. Can cause skin irritation.
[Invasive approach]: inhaled ingested percutaneous absorption
[Skin contact]: Immediately remove contaminated clothing, rinse thoroughly with plenty of flowing water.
[Eye contact]: immediately filed eyelid, with mobile water or saline for at least 15 minutes.
[Inhalation]: Quickly disengage from the scene to fresh air. Note that warm, breathing difficulties when oxygen. When breathing stops, perform artificial respiration immediately. Get medical attention.
[Ingestion]: When the patient awake immediately gargle, to drink milk or egg white. Get medical attention.
[Respiratory protection]: It may be exposed to vapor, it should wear gas masks. Emergency rescue or escape, wearing self-contained breathing apparatus.
[Eye protection]: Wear chemical safety glasses.
[Body protection]: wear appropriate protective clothing.
[Hand protection]: Wear chemical-resistant gloves.
[Conditions to Avoid]:
[Other protections]: Smoking, eating and drinking are prohibited at the work site. The site should be equipped with equipment for washing eyes and skin.
After work, rinse thoroughly. Separate storage of toxic contaminated clothing, washed and then.
[Safety and health standards]: China MAC: No standard set
Soviet MAC: No standard set
TWA: No standard set
STEL: No standard set
|
| Storage and Leakage Handling |
[Storage and transportation precautions]: Stored in a cool, ventilated warehouse. Keep away from fire and heat. Storage temperature should not exceed 30 ℃.
To prevent direct sunlight. Keep the container sealed. Should be oxidant, edible chemical raw materials stored separately.
Handling to light loading and unloading to prevent damage to packaging and containers. Pay attention to personal protection during packing and handling.
[Leak disposal]: evacuate people living in contaminated areas to a safe area, prohibit unrelated persons from entering the contaminated area, cut off the fire source.
Recommended emergency personnel wearing self-contained breathing apparatus, wear chemical protective clothing. Do not directly contact the spill, plugging to ensure safety.
Spray water to reduce evaporation. Mixed with sand or other non-flammable absorbent absorption, and then transported to the collection and disposal of waste disposal sites.
It can also be treated with an alkaline substance. Such as large leaks, the use of dike embankment, and then collect, transfer, recycling or harmless disposal.
[Engineering Control]: Strictly sealed to provide adequate local exhaust. As far as possible mechanization, automation.
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